氯化氰，又名氯甲氰，是一種化合物，化學(xué)式為CNCl，為無色液體或氣體，微甜，有劇du ，可溶于水、乙醇、乙mi等多數(shù)有機(jī)溶劑，溶于水后為弱酸性?；瘜W(xué)反應(yīng)活性很高，能與很多化學(xué)物質(zhì)發(fā)生反應(yīng)。受熱易分解，接觸水、水蒸氣時(shí)易發(fā)生反應(yīng)，甚至?xí)l(fā)生劇烈的反應(yīng)，同時(shí)會(huì)釋放出劇du和腐蝕性的煙霧?？膳c氫氧化鈉反應(yīng)生成氰酸鈉，與硫化鈉反應(yīng)生成硫氰酸鈉，與氨或胺類反應(yīng)生成氨基氰，與醇類反應(yīng)生成三聚氰酸酯。
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浩瀚色譜采用氣相色譜法測(cè)定工業(yè)廢氣中的氯化氰含量.采用GC790型氣相色譜儀,HH-CNCL-III色譜柱,采用外標(biāo)法定量.氯化氰濃度在0.1~10 mol/mol范圍內(nèi)與峰面積呈良好的線性關(guān)系,相關(guān)系數(shù)大于0.999,9次重復(fù)測(cè)定結(jié)果的相對(duì)標(biāo)準(zhǔn)偏差小于4%,樣品加標(biāo)回收率為95%~104%.結(jié)果表明該方法簡(jiǎn)單,快速,測(cè)試結(jié)果準(zhǔn)確可靠,滿足廢氣中氯化氰含量的測(cè)試.
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名稱：填充柱
固定相：專用
規(guī)格：3m*3mm
型號(hào)：HH-CNCL-III
應(yīng)用：工業(yè)氯化氰純度及雜質(zhì)測(cè)定
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Cyanide chloride, also known as chloromethyl cyanide, is a compound with the chemical formula CNCl. It is a colorless liquid or gas, slightly sweet, and highly soluble in most organic solvents such as water, ethanol, and ethyl alcohol. After dissolving in water, it becomes weakly acidic. The chemical reactivity is high and can react with many chemical substances. It is prone to decomposition when heated, and can react with water or steam, even causing violent reactions, while releasing strong and corrosive smoke. It can react with sodium hydroxide to produce sodium cyanate, with sodium sulfide to produce sodium thiocyanate, with ammonia or amines to produce cyanamide, and with alcohols to produce cyanurate.
Haohan Chromatography uses gas chromatography to determine the content of cyanide chloride in industrial waste gas. The GC790 gas chromatograph, HH-CNCL-III chromatographic column, and external standard method are used for quantification. The concentration of cyanide chloride shows a good linear relationship with peak area in the range of 0.1-10 mol/mol, with a correlation coefficient greater than 0.999. The relative standard deviation of 9 repeated measurements is less than 4%, and the sample recovery rate is 95%~104%. The results show that this method is simple, fast, accurate and reliable, and can meet the testing of cyanide chloride content in waste gas
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